tert butyl peroxy acetate
Molecular formula
C6 H12 O3
Molecular weight / g mol-1
132,2
CAS number
107-71-1
Temperature dependance: at constant pressure
k(T)p/s-1 = A * exp(-Ea/R*T)
A/s-1
3,35 E15
5,49 E15
7,05 E15
Ea/kJ mol-1
145,8 ± 3,6
148,3 ± 2,5
150,4 ± 1,7
valid for temperature range / °C
120 - 175
120 – 185
120 - 190
determined at p/bar
500
1000
2000
Pressure dependance at constant temperature
(∂ln k/∂p)T = - ΔV‡/(R*T)
ΔV‡/cm3 mol-1
21,59 – 3,88 E-3 * p/bar
valid for pressure range / bar
100 - 2500
determined at T/°C
170
Temperature and pressure dependance
k(p,T)/s-1 = C1 * exp[-(C2 + {C3 -C4 p/bar}*p/bar)/(T/K)]
k(p,T)/s-1 = 6,78E15 * exp[-(17714 + {0,2471 – 3,336E-5 * p/bar}*p/bar)/(T/K)]
valid for the temperature/°C and pressure/bar range
120 - 190 ; 100 - 2500
representing experimental data better than/%
5
Reference
