tert butyl peroxy neo decanoate
Molecular formula
C14 H28 O3
Molecular weight / g mol-1
244,4
CAS number
Temperature dependance: at constant pressure
k(T)p/s-1 = A * exp(-Ea/R*T)
A/s-1
1,22 E14
Ea/kJ mol-1
116,8 ± 3,3
valid for temperature range / °C
95 - 120
determined at p/bar
2000
Pressure dependance at constant temperature
(∂ln k/∂p)T = - ΔV‡/(R*T)
ΔV‡/cm3 mol-1
1,7 ± 0,6
valid for pressure range / bar
250 - 2000
determined at T/°C
110
Temperature and pressure dependance
k(p,T)/s-1 = C1 * exp[-(C2 + {C3 -C4 p/bar}*p/bar)/(T/K)]
k(p,T)/s-1 = 1,22E14 * exp[-(14011 + {0,0208 – 0 * p/bar}*p/bar)/(T/K)]
valid for the temperature/°C and pressure/bar range
95 - 120 ; 250 - 2000
representing experimental data better than/%
6
Reference
