tert butyl peroxy 3,5,5-trimethyl hexanoate
Molecular formula
C13 H26 O3
Molecular weight / g mol-1
230,3
CAS number
13122-18-4
Temperature dependance: at constant pressure
k(T)p/s-1 = A * exp(-Ea/R*T)
A/s-1
56,9 E14
Ea/kJ mol-1
147,7 ± 2,4
valid for temperature range / °C
145 - 170
determined at p/bar
2000
Pressure dependance at constant temperature
(∂ln k/∂p)T = - ΔV‡/(R*T)
ΔV‡/cm3 mol-1
14,5 – 5,78 E-3 * p/bar
valid for pressure range / bar
250 - 2000
determined at T/°C
165
Temperature and pressure dependance
k(p,T)/s-1 = C1 * exp[-(C2 + {C3 -C4 p/bar}*p/bar)/(T/K)]
k(p,T)/s-1 = 4,44E15 * exp[-(17465 + {0,208 – 5,36E-5 * p/bar}*p/bar)/(T/K)]
valid for the temperature/°C and pressure/bar range
145 – 170 ; 250 - 2000
representing experimental data better than/%
2
Reference
