tert butyl peroxy 2-ethyl hexanoate
Molecular formula
C12 H24 O3
Molecular weight / g mol-1
216,3
CAS number
3006-82-4
Temperature dependance: at constant pressure
k(T)p/s-1 = A * exp(-Ea/R*T)
A/s-1
4,10 E14
Ea/kJ mol-1
129,6 ± 1,0
valid for temperature range / °C
125 - 155
determined at p/bar
1000
Pressure dependance at constant temperature
(∂ln k/∂p)T = - ΔV‡/(R*T)
ΔV‡/cm3 mol-1
3,6 ± 1,1
valid for pressure range / bar
250 - 2000
determined at T/°C
145
Temperature and pressure dependance
k(p,T)/s-1 = C1 * exp[-(C2 + {C3 -C4 p/bar}*p/bar)/(T/K)]
k(p,T)/s-1 = 4,10E14 * exp[-(15541 + {0,0433 – 0 * p/bar}*p/bar)/(T/K)]
valid for the temperature/°C and pressure/bar range
125 - 155 ; 250 - 2000
representing experimental data better than/%
3
Reference
