tert butyl peroxy pivalate
Molecular formula
C9 H18 O3
Molecular weight / g mol-1
174,2
CAS number
927-07-1
Temperature dependance: at constant pressure
k(T)p/s-1 = A * exp(-Ea/R*T)
A/s-1
6,1 E14
Ea/kJ mol-1
125,4 ± 3,9
valid for temperature range / °C
110 - 145
determined at p/bar
2000
Pressure dependance at constant temperature
(∂ln k/∂p)T = - ΔV‡/(R*T)
ΔV‡/cm3 mol-1
3,0 ± 0,9
valid for pressure range / bar
100 - 2500
determined at T/°C
125
Temperature and pressure dependance
k(p,T)/s-1 = C1 * exp[-(C2 + {C3 -C4 p/bar}*p/bar)/(T/K)]
k(p,T)/s-1 = 6,10E14 * exp[-(15011 + {0,0367 – 0 * p/bar}*p/bar)/(T/K)]
valid for the temperature/°C and pressure/bar range
110 – 145 ; 100 - 2500
representing experimental data better than/%
3
Reference
