tert butyl peroxy propionate
Molecular formula
C7 H14 O3
Molecular weight / g mol-1
146,2
CAS number
Temperature dependance: at constant pressure
k(T)p/s-1 = A * exp(-Ea/R*T)
A/s-1
12,9 E14
Ea/kJ mol-1
142,3 ± 1,9
valid for temperature range / °C
150 - 185
determined at p/bar
500
Pressure dependance at constant temperature
(∂ln k/∂p)T = - ΔV‡/(R*T)
ΔV‡/cm3 mol-1
11,4 – 2,47 E-3 * p/bar
valid for pressure range / bar
100 - 2000
determined at T/°C
170
Temperature and pressure dependance
k(p,T)/s-1 = C1 * exp[-(C2 + {C3 -C4 p/bar}*p/bar)/(T/K)]
k(p,T)/s-1 = 1,42E15 * exp[-(17087 + {0,145 – 2,03E-5 * p/bar}*p/bar)/(T/K)]
valid for the temperature/°C and pressure/bar range
150 – 185 ; 100 - 2000
representing experimental data better than/%
2
Reference
