Bergert, U.; Buback, M.; Heyne, J.
Pressure and temperature dependence of the propagation rate coefficient in free-radical polymerization of butyl methacrylate
Macromol. Rapid Comm. 1995, 16, 275-281.
 

The propagation rate coefficient in free-radical bulk polymerization of butyl methacrylate has been studied at temperatures between -10 °C and 60 °C up to a maximum pressure of 2 000 bar. The data were obtained by means of the PLP-GPC technique which combines pulsed-laser polymerization with product analysis by gel-permeation chromatography.