Bergert, U.; Beuermann, S.; Buback, M.; Kurz, C. H.; Russell, G. T.; Schmaltz, C.
Effect of photoinitiator on the molar mass distribution obtained from a pulsed laser polymerization
Macromol. Rapid Comm. 1995, 16, 425-434.
 

The propagation rate coefficient in free-radical bulk polymerization of butyl methacrylate has been studied at temperatures between -10°C and 60°C up to a maximum pressure of 2 000 bar. The data were obtained by means of the PLP-GPC technique which combines pulsed-laser polymerization with product analysis by gel-permeation chromatography.